N-alpha-t-Butyloxycarbonyl-N-epsilon-nosyl-L-lysine | CAS 1301706-36-4

Element: butyloxycarbonyl epsilon lysine alpha nosyl

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C-S » Chemicals » alpha-butyloxycarbonyl-epsilon-nosyl-lysine-PX2567295

Identification

N-alpha-t-Butyloxycarbonyl-N-epsilon-nosyl-L-lysine

CAS:

1301706-36-4

EINECS:

Molecular Formula:

C₁₇H₂₅N₃O₈S

MDL:

MFCD13184901

Synonym:

Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.

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Boc-L-Lys(Ns)-OH

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N-alpha-tert-Butyloxycarbonyl-N-epsilon-nosyl-L-lysine

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BAA5230.0005

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