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N-alpha-(9-Fluorenylmethyloxycarbonyl)-D-aspartic acid beta allyl ester

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Formula: C22H21NO6
CAS: 177609-12-0
search Element: fluorenylmethyloxycarbonyl aspartic allyl alpha ester acid beta
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Identification

Structural Formula
N-alpha-(9-Fluorenylmethyloxycarbonyl)-D-aspartic acid beta allyl ester
CAS:
177609-12-0
EINECS:
Molecular Formula:
C22H21NO6
MDL:
MFCD01074688
Synonym:
fmoc-d-asp(all)-oh ; fmoc-d-asp(oai)-oh ; fmoc-d-asp(oal)-oh ; fmoc-d-asp(oall)-oh ; fmoc-d-aspartic acid-allyl ester ; fmoc-d-aspartic acid beta-allyl ester ; n-alpha-(9-fluorenylmethyloxycarbonyl)-d-aspartic acid beta allyl ester ; (r)-2-(((9h-fluoren-9-yl)methoxy)carbonylamino)-4-(allyloxy)-4-oxobutanoic acid ; d-aspartic acid, n-[(9h-fluoren-9-ylmethoxy)carbonyl]-, 4-(2-propenyl) ester


Description

Building block with side protection orthogonal to Fmoc/tBu strategy. Can be used for side specific derivatization, for example for TFA mediated in situ cyclization, which is taking advantage of intermediate aspartamide formation. Reference: A Tandem In Situ Peptide Cyclization through Trifluoroacetic Acid Cleavage; Koushik Chandra, Tapta Kanchan Roy, Deborah E. Shalev, Abraham Loyter, Chaim Gilon, R. Benny Gerber, and Assaf Friedler; Angew. Chem. Int. Ed. 2014; 53: 9450-9455. DOI: 10.1002/anie.201402789.


Suppliers

Iris Biotech GmbH
FAA1308
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Prices & Availability




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Properties for N-alpha-(9-Fluorenylmethyloxycarbonyl)-D-aspartic acid beta allyl ester

Molecular Weight:
395.41 g·mol−1
Melting point:
105-116°C
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Alternative Distributors of [N-alpha-(9-Fluorenylmethyloxycarbonyl)-D-aspartic acid beta allyl ester]

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MSDS:
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