N-alpha-(9-Fluorenylmethyloxycarbonyl)-beta,beta-dimethyl-L-methionine

Element: fluorenylmethyloxycarbonyl methionine dimethyl alpha beta beta

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C-S » Chemicals » alpha-fluorenylmethyloxycarbonyl-beta-beta-dimethyl-methionine-PX1829670

Identification

N-alpha-(9-Fluorenylmethyloxycarbonyl)-beta,beta-dimethyl-L-methionine

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Description

beta,beta-Dimethylation of amino acids stabilizes appropriate peptides towards digestion by proteases. Reference: Total synthesis of the large non-ribosomal peptide polytheonamide B; Masayuki Inoue, Naoki Shinohara, Shintaro Tanabe, Tomoaki Takahashi, Ken Okura, Hiroaki Itoh, Yuki Mizoguchi, Maiko Iida, Nayoung Lee and Shigeru Matsuoka; Nature Chem. 2010; 2: 281-285. DOI: 10.1038/nchem.554.

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