n-Butyllithium, 2.5M solution in hexanes | CAS 109-72-8

Element: butyllithium solution hexanes

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Identification

n-Butyllithium, 2.5M solution in hexanes

CAS:

109-72-8

EINECS:

203-698-7

Molecular Formula:

C₄H₉Li

MDL:

MFCD00009414

Synonym:

æ£ä¸åŸºé”‚(1.6mol) ; n-butyllithium ; æ£ä¸åŸºé”‚2.5m ; butyllithium ; butyl-lithiu ; lithiumbutyl ; n-buli ; n-utyllithium ; æ£ä¸åŸºé”‚1.6m ; æ£ä¸åŸºé”‚ ( 2.5mol )

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Prices & Availability

Data is processed

Properties for n-Butyllithium, 2.5M solution in hexanes

Molecular Weight:

64.06 g·mol−1

Density:

0.68 g/mL at 20 °C

Melting point:

-95 °C

Boiling point:

80 °C

Flash point:

10 ºF

Hazard Statements

GHS02
Flammable

Flammable gases, category 1
Flammable aerosols, categories 1, 2
Flammable liquids, categories 1, 2, 3
Flammable solids, categories 1, 2
Self-reactive substances and mixtures, types B, C, D, E, F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Combustible solids, category 3
Combustible liquids, category 3
Self-heating substances and mixtures, categories 1, 2
Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
Organic peroxides, types B, C, D, E, F

GHS05
Corrosive

Corrosive to metals, category 1

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used

with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization

GHS08
Health hazard

Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A, 1B, 2
Carcinogenicity, categories 1A, 1B, 2
Reproductive toxicity, categories 1A, 1B, 2
Specific target organ toxicity following single exposure, categories 1, 2
Specific target organ toxicity following repeated exposure, categories 1, 2
Aspiration hazard, categories 1, 2

GHS09
Environmental hazard

Acute hazards to the aquatic environment, category 1
Chronic hazards to the aquatic environment, categories 1, 2
Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:

R11 - Highly flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R17 - Spontaneously flammable in air
R34 - Causes burns
R35 - Causes severe burns
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R63 - Possible risk of harm to the unborn child
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness

Safety Codes:

S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46 - If swallowed, seek medical advice immediately and show this container or label
S5 - Keep contents under ... (appropriate liquid to be specified by the manufacturer)
S6 - Keep under ... (inert gas to be specified by the manufacturer)
S60 - This material and its container must be disposed of as hazardous waste
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place

Hazard Classes:

4.3

Hazard Symbols:

F, C, N

Storage temperature :

2-8°C

RID/ADR certification :

UN 3399 4.3 / PG 1

Alternative Distributors of [n-Butyllithium, 2.5M solution in hexanes]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

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Mol File:

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MSDS:

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