(1S)-(+)-3-Carene | CAS 498-15-7

Element: carene

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Identification

(1S)-(+)-3-Carene

CAS:

498-15-7

EINECS:

207-856-6

Molecular Formula:

C₁₀H₁₆

MDL:

MFCD00066417

SMILES:

CC1=CC[C@@H]2[C@H](C1)C2(C)C

Synonym:

(1s,6α)-3,7,7-trimethylbicyclo[4.1.0]hept-3-ene ; (1s)-(+)-3-carene 99% ; (+)-3-carene, terpene standard ; (1s)-(+)-3-carene ; (1s)-3,7,7-trimethylbicyclo[4.1.0]hept-3-ene ; (1s,6r)-3-carene ; einecs 207-856-6 ; (+)-3-carene ; (1s)-(+)-car-3-ene ; 3-carene, (1s,6r)-(+)-

Description

(1S)-(+)-3-Carene is a chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene.(1S)-(+)-3-Carene has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry.. (1S)-(+)-3-Carene is a precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.

Suppliers

AK Scientific, Inc.

AS12923876

Santa Cruz Biotechnology, Inc.

251652

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Prices & Availability

Data is processed

Properties for (1S)-(+)-3-Carene

Molecular Weight:

136.23 g·mol−1

Density:

0.865 g/mL at 25 °C(lit.)

Boiling point:

170-172 °C(lit.)

Flash point:

131 ºF

Hazard Statements

GHS02
Flammable

Flammable gases, category 1
Flammable aerosols, categories 1, 2
Flammable liquids, categories 1, 2, 3
Flammable solids, categories 1, 2
Self-reactive substances and mixtures, types B, C, D, E, F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Combustible solids, category 3
Combustible liquids, category 3
Self-heating substances and mixtures, categories 1, 2
Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
Organic peroxides, types B, C, D, E, F

GHS03
Harmful

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, categories 2, 3
Eye irritation, category 2A
Skin sensitization, category 1
Specific target organ toxicity following single exposure, category 3
- Respiratory tract irritation
- Narcotic effects

Not used

with the "skull and crossbones" pictogram
for skin or eye irritation if:
the "corrosion" pictogram also appears
the "health hazard" pictogram is used to indicate respiratory sensitization

GHS08
Health hazard

Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A, 1B, 2
Carcinogenicity, categories 1A, 1B, 2
Reproductive toxicity, categories 1A, 1B, 2
Specific target organ toxicity following single exposure, categories 1, 2
Specific target organ toxicity following repeated exposure, categories 1, 2
Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:

R10 - Flammable
R43 - May cause sensitisation by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Safety Codes:

S36/37 - Wear suitable protective clothing and gloves
S60 - This material and its container must be disposed of as hazardous waste
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet

Hazard Symbols:

Xi, N

Storage temperature :

?20 °C

RID/ADR certification :

UN 2319 3 / PG 3

Alternative Distributors of [(1S)-(+)-3-Carene]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Suzhou Rovathin Pharmatech Co., Ltd | Jinan Great Chemical Co., Ltd. | East Chemical Industry Co., Ltd.