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(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)

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Formula: C45H44Cl2F6P3Rh 4*
CAS: 35238-97-2
search Element: hexafluorophosphate triphenylphosphine dichloromethane cyclooctadiene complex rhodium
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Identification

Structural Formula
(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)
CAS:
35238-97-2
EINECS:
Molecular Formula:
C45H44Cl2F6P3Rh 4*
MDL:
SMILES:
C1C[CH][CH]CC[CH][CH]1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C(Cl)Cl.F[P-](F)(F)(F)(F)F.[Rh]
Synonym:
(1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1) ; (1,5-cyclooctadiene)bis(triphenylphos-phine)rhodi ; (1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOS-PH INE)RHODIUM(I) PF6 CH2CL2 (1:1) ; (1,5-cyclooctadiene)bis(triphenylphosphine)rhodium(i) hexafluorophosphate dichloromethane complex (1:1) ; (1,5-cyclooctadiene)bis(triphenylphosphine)rhodium(I) PF6/


Description

(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) is a preparation of rhodium complexed with 1,5-COD and two PPh3 ligands. This complex has been described as a catalyst for the selective homogenous hydrogenation of benzothiophene and quinoline.


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Properties for (1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)

Molecular Weight:
965.55 g·mol−1
Melting point:
215 °C(lit.)
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Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37/39 - Wear suitable gloves and eye/face protection
Hazard Symbols:
Xi
Hazard symbol Xi
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Alternative Distributors of [(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)]

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