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Gadolinium(III) tris(isopropoxide)

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Formula: C9H21GdO3
CAS: 14532-05-9

Identification

Structural Formula
Gadolinium(III) tris(isopropoxide)
CAS:
14532-05-9
EINECS:
Molecular Formula:
C9H21GdO3
MDL:
MFCD00144381
Synonym:
tris(isopropoxy) gadolinium(iii) ; gadolinium tri-i-propoxide ; gadolinium(iii)i-propoxide(99.9%-gd)(reo) ; gadolinium isopropoxide ; gadolinium(iii) i-propoxide 99.9%-gd) ; gadolinium(iii) i-propoxide ; (99.9%-gd)(reo) ; gadolinium(iii) tris(isopropoxide) ; gadolinium i-propoxide ; gadolinium (iii) isopropoxide


Description

A catalyst used in a ring opening of meso-aziridines with trimethylsilyl azide. In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.


Suppliers

Santa Cruz Biotechnology, Inc.
257552
Dayang Chem (Hangzhou) Co.,Ltd.
DC421616864
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Properties for Gadolinium(III) tris(isopropoxide)

Molecular Weight:
334.51 g·mol−1
Melting point:
>300 °C
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Hazard Statements

GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Risk Codes:
R36/37/38 - Irritating to eyes, respiratory system and skin
Safety Codes:
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37/39 - Wear suitable gloves and eye/face protection
Hazard Classes:
4.1
Hazard Symbols:
Xi
Hazard symbol Xi
RID/ADR certification :
UN3180
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Alternative Distributors of [Gadolinium(III) tris(isopropoxide)]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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