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Lithium, phenyl-

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Formula: C6H5Li
CAS: 591-51-5
search Element: lithium phenyl

Identification

Structural Formula
Lithium, phenyl-
CAS:
591-51-5
EINECS:
209-720-1
Molecular Formula:
C6H5Li
MDL:
MFCD00014254
SMILES:
[Li]c1ccccc1
Synonym:
phenyllithium ; phenyllithium dibutyl ; phenyllithium, 1.5-1.7m in cyclohexane/ether ; lithiobenzene ; phenyl-lithiu ; phenyllithium solution ; 20%solutionindibutylether ; phenyllithium solution 20% in dibutylether ; lithiumphenyl ; phli




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Properties for Lithium, phenyl-

Molecular Weight:
84.05 g·mol−1
Density:
0.835 g/mL at 25 °C
Boiling point:
140-143 °C
Flash point:
20 °C
Physical Description:
dark brown to black solution
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R14 - Reacts violently with water
R17 - Spontaneously flammable in air
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R34 - Causes burns
R35 - Causes severe burns
R36/37/38 - Irritating to eyes, respiratory system and skin
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S6 - Keep under ... (inert gas to be specified by the manufacturer)
S60 - This material and its container must be disposed of as hazardous waste
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S8 - Keep container dry
Hazard Classes:
4.3
Hazard Symbols:
F, C, N, Xi
Hazard symbol C Hazard symbol N Hazard symbol F Hazard symbol Xi
Storage temperature :
2-8°C
RID/ADR certification :
UN 3392 4.2 / PG 1
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Alternative Distributors of [Lithium, phenyl-]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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Downloads

Mol File:
-/-
MSDS:
-/-