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Sodium aluminium hydride

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Formula: AlH4 . Na
CAS: 13770-96-2

Identification

Structural Formula
Sodium aluminium hydride
CAS:
13770-96-2
EINECS:
237-400-1
Molecular Formula:
AlH4 . Na
MDL:
MFCD00192443
Synonym:
aluminate(1-),tetrahydro-, sodium (1:1), (t-4)- ; aluminate(1-), tetrahydro-, sodium, (t-4)- (9ci) ; sah22 ; sah ; sodium tetrahydroaluminate ; sodium tetrahydridoaluminate(1-) ; sodiumaluminum hydride ; sodium aluminum hydride ; sodium tetrahydraluminate ; sodium aluminumtetrahydride ; aluminiumsodiumhydride ; sodium aluminium hydride ; sodiumaluminumtetrahydride ; sodium aluminum hydride (naalh4) ; aluminate(1-),tetrahydro-, sodium (8ci) ; sodium tetrahydroaluminate (naalh4) ; natriumtetrahydridoaluminat ; sodium tetrahydroaluminate(1-) ; aluminum sodium hydride (alnah4) (6ci) ; aluminum sodium tetrahydride ; sodiumtetrahydroaluminate ; aluminumsodiumhydride




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Properties for Sodium aluminium hydride

Molecular Weight:
54.01 g·mol−1
Density:
0.905 g/mL at 25 °C
Melting point:
178 °C
Flash point:
-10 °C
Transport Information:
UN 2835 4
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Flammable when exposed to heat or flame. May ignite and explode on contact with water. Reacts violently with tetrahydrofuran when heated. When heated to decomposition it emits toxic fumes of Na2O. See also ALUMINUM COMPOUNDS and HYDRIDES.
Risk Codes:
R11 - Highly flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R34 - Causes burns
R36/37/38 - Irritating to eyes, respiratory system and skin
R40 - Limited evidence of a carcinogenic effect
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S33 - Take precautionary measures against static discharges
S36/37 - Wear suitable protective clothing and gloves
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S7/8 - Keep container tightly closed and dry
Hazard Classes:
4.3
Hazard Symbols:
Severe fire and explosion risk in contact with oxidizing agents and water, forms caustic and irritating compounds.

Storage temperature :
water-free area
RID/ADR certification :
UN 2835 4.3 / PG 2
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Alternative Distributors of [Sodium aluminium hydride]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Skyrun Industrial Co., Ltd.

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Downloads

Mol File:
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MSDS:
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