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tert-Butyllithium,1.3M in pentane

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Formula: C4H9Li
CAS: 594-19-4

Identification

Structural Formula
tert-Butyllithium,1.3M in pentane
CAS:
594-19-4
EINECS:
209-831-5
Molecular Formula:
C4H9Li
MDL:
MFCD00008795
Synonym:
1,1-dimethyl-ethane-lithium ; tert-butyllithium solution ; (1,1-dimethylethyl)lithium ; t-butyllithium ; t-buli ; nominally1.5minn-pentane ; lithium tert-butyl ; (1,1-dimethylethyl)-lithium ; (1,1-dimethylethyl)-lithiu ; tert-butyllithium




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Lithium, (1,1-dimethylethyl)-
Angene International Limited
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Merck Schuchardt OHG
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tert-Butyllithium, nominally 1.5M in n-pentane
Alfa (A Johnson Matthey Company)
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tert-Butyllithium, nominally 1.5M in n-pentane, packaged under Argon in resealable ChemSeal bottles
Alfa (A Johnson Matthey Company)
A38016114048

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Properties for tert-Butyllithium,1.3M in pentane

Molecular Weight:
64.06 g·mol−1
Density:
0.69 g/mL at 20 °C
Boiling point:
36-40 °C
Flash point:
20 ºF
Physical Description:
colourless to pale yellow solution
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
GHS09

GHS09
Environmental hazard
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R15 - Contact with water liberates extremely flammable gases
R17 - Spontaneously flammable in air
R34 - Causes burns
R38 - Irritating to skin
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S33 - Take precautionary measures against static discharges
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place
Hazard Classes:
4.3
Hazard Symbols:
F, C, N
Hazard symbol C Hazard symbol N Hazard symbol F
Storage temperature :
2-8°C
RID/ADR certification :
UN 3394 4.2 / PG 1
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Alternative Distributors of [tert-Butyllithium,1.3M in pentane]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Jinan Great Chemical Co., Ltd. | Chemwill Asia Co.,Limited | Xiang Ding Chemical International Co., Ltd | Yongyi Chemicals Group Co., Ltd. | BOC Sciences | Suzhou Vosun Chemical Co.,Ltd. | scienTEST

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