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(TRIMETHYLSILYL)DIAZOMETHANE

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Formula: C4H10N2Si
CAS: 18107-18-1

Identification

Structural Formula
(TRIMETHYLSILYL)DIAZOMETHANE
CAS:
18107-18-1
EINECS:
Molecular Formula:
C4H10N2Si
MDL:
MFCD00053946
Synonym:
(trimethylsilyl)diazomethanesolution ; (ca. 10% in hexane, ca. 0.6mol/l) ; (trimethylsilyl)diazomethane ; (diazomethyl)trimethylsilane ; trimethylsilyldiazomethane  ; tms-diazomethane ; trimethylsilyl)diazomethan ; silane,(diazomethyl)trimethyl- ; diazo(trimethylsilyl)methane ; trimethyl(diazomethyl)silane




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Properties for (TRIMETHYLSILYL)DIAZOMETHANE

Molecular Weight:
114.22 g·mol−1
Density:
0.773 g/mL at 25 °C
Boiling point:
96 °C
Flash point:
-31 ºF
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS06

GHS06
Toxic
  • Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
GHS08

GHS08
Health hazard
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
GHS09

GHS09
Environmental hazard
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R12 - Extremely flammable
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R23 - Toxic by inhalation
R26 - Very toxic by inhalation
R38 - Irritating to skin
R39/26 - Very Toxic: danger of very serious irreversible effects through inhalation
R45 - May cause cancer
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 - Possible risk of impaired fertility
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S28 - After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S29 - Do not empty into drains
S33 - Take precautionary measures against static discharges
S36/37 - Wear suitable protective clothing and gloves
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S53 - Avoid exposure - obtain special instructions before use
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S9 - Keep container in a well-ventilated place
Hazard Classes:
3
Hazard Symbols:
F+, Xn, N, F, T, T+
Hazard symbol T Hazard symbol N Hazard symbol F+ Hazard symbol F Hazard symbol Xn Hazard symbol T+
Storage temperature :
Refrigerator
RID/ADR certification :
UN 1208 3 / PG 2
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Alternative Distributors of [(TRIMETHYLSILYL)DIAZOMETHANE]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Gelest, Inc. | Jinan Great Chemical Co., Ltd. | Boron Molecular | Ruiyi Medical Co., Ltd. | ForeChem Ltd. | 3Way Pharm Inc. | Suzhou Sibian Chemical Technology Co., Ltd. | BOC Sciences | Jinan Haohua Industry Co., Ltd. | Yangzhou Princechem Co., Ltd. | Amadis Chemical Co., Ltd. | Wanko Chemical Co., Ltd.

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