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Tris(N,N-bis(trimethylsilyl)amide)samarium(III)

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Formula: Sm(N(Si(CH3)3)2)3
CAS: 35789-01-6

Identification

Structural Formula
Tris(N,N-bis(trimethylsilyl)amide)samarium(III)
CAS:
35789-01-6
EINECS:
Molecular Formula:
Sm(N(Si(CH3)3)2)3
MDL:
MFCD03427097
Synonym:
tris[n,n-bis(trimethylsilyl)amide]samarium ; tris[n,n-bis(trimethylsilyl)amide]samarium [[(ch3)3si]2n]3sm fw 631.51 m.p. 93-1060c ; samarium tris(hexamethyldisilazide) ; tris[n,n-bis(trimethylsilyl)amide]samarium(iii) ; 1,1,1-trimethyl-n-(trimethylsilyl)silanamine samarium(iii) salt ; tris[n,n-bis(trimethylsilyl)amide]samarium [[(ch3)3si]2n]3sm ; tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium ; samarium tris(hexamethylsilazide)




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Properties for Tris(N,N-bis(trimethylsilyl)amide)samarium(III)

Molecular Weight:
631.51 g·mol−1
Melting point:
93-106 °C(lit.)
Boiling point:
83-4 °C/1x10-4mmHg
Flash point:
36 ºF
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Hazard Statements

GHS02

GHS02
Flammable
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F
GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1

Safety & Transport Information

Risk Codes:
R11 - Highly flammable
R14/15 - Reacts violently with water, liberating extremely flammable gases
R34 - Causes burns
Safety Codes:
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S43 - In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S7/8 - Keep container tightly closed and dry
Hazard Symbols:
F, C
Hazard symbol C Hazard symbol F
RID/ADR certification :
UN 3396 4.3 / PG 2
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Alternative Distributors of [Tris(N,N-bis(trimethylsilyl)amide)samarium(III)]

Producers or manufacturers change the product range from time to time. Currently there are no other manufacturers known.
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MSDS:
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